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Photoinitiated Polymerization

ISBN-10:0-8412-3813-8
ISBN-13:978-0-8412-3813-8

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Description

General descriptionPhotoinitiated Polymerization is divided into five sections. Free radical photopolymerizations command most of the interest and activity within the field and thus is discussed first. The second section discusses kinetic studies of the mechanism of free radical polymerizations. The third section covers cationic photopolymerizations, which along with free radical polymerizations, are being used in many industrial applications. The fourth section is devoted to recent developments in novel photopolymeriztion chemistry. This section describes new photobase generators, developments in monomers, oligomers and templated polymerizations of liquid crystal polymers. Finally, the fifth section portrays new and emerging applications for photopolymerizations.

Properties

publication infoK. Belfield and J. Crivello, Oxford University Press, 2003, 584 pp., hard cover

Table Of Contents

Table of ContentsFree Radical Photopolymerization Chemistry
1. N-Vinylamides and Reduction of Oxygen Inhibition in Photopolymerization of Simple Acrylate Formulations
2. Spectroscopic Investigation of Three-Component Initiator Systems
3. A Mechanistic Description of the Sensitized N-Substituted Maleimide Initiated Photopolymerization of an Acrylate Monomer
4. Photoinitiation of Acrylates via Sensitized Phthalimide Derivatives,
5. Photoinitiated Polymerization of Selected Thiol-ene Systems.
6. Allyl Ethers in the Thiol-ene Reaction
7. Mechanistic Aspects of Maleimide-Donor Photocopolymerizations
Kinetic Studies of Free Radical Photopolymerizations
8. Photoinitiated Cross-Linking Polymerization of Monomer Blends
9. Synthesis and Photochemistry of Monodisperse Oligomeric-Polymeric Photoinitiators
10. Kinetics of Photopolymerization of Acrylate Coatings
11. Effect of Preorganization Due to Hydrogen Bonding on the Rate of Photoinitiated Acrylate Polymerization
12. Photoinitiator Triplet States and Photoinitiating Radical-Monomer Interactions: Investigation through Time-Resolved Photothermal Techniques
13. Oxygen Inhibition Effect on Surface Properties of UV-Curable Acrylate Coatings,
14. Oxygen and Radical Photopolymerization in Films
Cationic Photopolymerization
15. Synergistic Free Radical Effects in Photoinitiated Cationic Polymerization
16. Initiation of Cationic Polymerization by Addition-Fragmentation Reactions: Bifunctional Addition-Fragmentation Agents as Photoinitiators for Cationic Polymerization
17. Diazonium Salts as Cationic Photoinitiators: Radical and Cationic Aspects
18. 2,3-Dihydrofuran: A Special Vinyl Ether for Cationic Photopolymerization
19. Photosensitization of Onium Salt Initiated Cationic Photopolymerizations by Carbazole Monomers, Polymers, and Oligomers
20. Phenothiazine Photosensitizers for Onium Salt Photoinitiated Cationic Polymerization
21. Visible and Long-Wavelength Cationic Photopolymerization,
22. Synthesis and Photoinitiated Cationic Polymerization of Organic-Inorganic Hybrid Resins
23. The Photoinitiated Cationic Polymerization of 3,4-Epoxy-1-butene
24. Synthesis and Photoinitiated Cationic Polymerization of Fluoroalkyl Propenyl Ethers
25. Cationic Photopolymerization of 2-Phenyloxetanes
26. Photocurable Pressure-Sensitive Adhesives Using Alkyl Oxetane
27. Photocationic Curable Silsesquioxanes Having Oxetanyl Group
28. Thermomechanical Studies of Photoinitiated Cationic Polymerization of a Cycloaliphatic Epoxy Resin
New Photopolymerization Chemistry
29. Harvesting the Fields of Inorganic and Organometallic Photochemistry for New Photoinitiators
30. Quaternary Ammonium N,N-Dimethyldithiocarbamates as Photobase Generators
31. Synthesis and Photochemical Reaction of High-Performance UV-Curing Oligomers
32. Photopolymerization Kinetics of Nanostructured Polymers Templated by Lyotropic Liquid Crystals
33. Photopolymerization of Silica-Filled Composites: Encapsulants for Microelectronic Devices
34. Photocurable, Hydrophobic Oligomers Based on Liquid Polybutadienes
35. UV-Curable Acrylated Oligomers: Effect of Structural Variation on Liquid and Cured Film Properties
36. Real-Time Fluorescence for Determining the Relative Sensitivities of Reactive and Non-Reactive Fluorescent Probes
37. Continuous Photopolymerization in a Novel Thin Film Spinning Disc Reactor
38. Pulsed Laser Polymerization of Methyl Methacrylate Using Wilkinson's Catalyst as a Photoinitiator
New and Emerging Applications for Photoinitiating Polymerizations
39. Two-Photon Photoinitiated Polymerization
40. Fluorinated Distyrylbenzene Containing
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